150(77) REVOKED Recommendation for material safety data sheets for MARPOL Annex I cargoes and marine fuel oils

Annex 1 Material Safety Data Sheets (MSDS) For marine use suitable to meet the particular needs of the marine industry containing safety, handling and environmental information to be supplied to a ship prior to the loading of MARPOL Annex I type cargoes and marine fuel oils

1	Identification of the substance or mixture and of the supplier	• Name of the category - see supporting guidelines for each Annex I category type • The name of the substances • Trade name of the substances • Description of Bill of Lading (B/L) • Other means of identification. • Supplier.s details (including name, address, phone number etc). • Emergency phone number.
2	Hazards identification	• GHS classification of the substance/mixture and any regional information. • Other hazards which do not result in classification (e.g. dust explosion hazard) or are not covered by the GHS.
3	Composition/information on ingredients*	• Common name, synonyms etc. • Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance. • The chemical identity and concentration or concentration ranges of all ingredients which are hazardous within the meaning of the GHS.* • See supporting guidelines for each Annex I category type.
4	First aid measures	• Description of necessary measures, subdivided according to the different routes of exposure, i.e. inhalation, skin and eye contact and ingestion. • Most important symptoms/effects, acute and delayed. • Indication of immediate medical attention and special treatment needed, if necessary
5	Fire-fighting measures	• Suitable extinguishing media. • Special protective equipment and precautions for fire-fighters
6	Accidental release measures	• Personal precautions, protective equipment and emergency procedures. • Environmental precautions. • Methods and materials for containment and cleaning up.
7	Handling and storage	• Precautions for safe handling. • Conditions for safe storage, including any incompatibilities.
8	Exposure controls/personal protection.	• Control parameters e.g. occupational exposure limit values • Appropriate technical precautions. • Individual protection measures, such as personal protective equipment
9	Actual physical, [and] chemical and operational properties	• See supporting guidelines for each Annex I category type
10	Stability and reactivity	• Chemical stability. • Possibility of hazardous reactions. • Conditions to avoid (e.g. static discharge).
11	Toxicological information	• Concise but complete and comprehensible description of the various toxicological (health) effects and the available data used to identify those effects, including: • Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact); • Symptoms related to the physical, chemical and toxicological characteristics; • Delayed and immediate effects and also chronic effects from short- and long-term exposure. • Numerical measures of toxicity (such as acute toxicity estimates)
12	Ecological information	• Ecotoxicity (aquatic and terrestrial, where available). • Persistence and degradability • Bioaccumulative potential • Mobility in soil • Other adverse effects
13	Disposal considerations	• Description of waste residues and information on their safe handling and methods of disposal, in line with MARPOL requirements.
14	Transport information	• UN number • UN Proper shipping name. • Transport Hazard class(es). • Special precautions which a user needs to be aware of or needs to comply with in connection with transport (e.g. heating and carriage temperatures)
15	Regulatory information	• Safety, health and environmental regulations specific for the product in question.
16	Other information including information on preparation and revision of the MSDS	• Version No. • Date of issue • Issuing source

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* Note: For information on ingredients, the competent authority rules for CBI take priority over the rules for product identification.

Annex 2 Guidelines for the completion of MSDS for the MARPOL Annex 1 type cargoes and marine fuel oils

1 Categories of liquids

The following categories subdivide the full scope of substances covered by Annex I of MARPOL 73/78 and set in groups specific products for general identification purposed to define the technical and environmental parameters required for the MSDS.

1. crude oils;
   
   
2. fuel and residual oils, including ship.s bunkers (ISO 8217, table 2);
   
   
3. unfinished distillates, hydraulic oils and lubricating oils;
   
   
4. gas oils, including ship.s bunkers (ISO 8217, table 1);
   
   
5. kerosenes;
   
   
6. napthas and condensates;
   
   
7. gasoline blending stocks;
   
   
8. gasolines and spirits; and
   
   
9. asphalt solutions.

2 Outline of technical, physical and environmental properties

2.1 The following properties should be reported for all liquids categorized in paragraph 1:

.1 Technical properties:

Density at 15ºC - kg/m3 Sulphur content % mass Benzene content - mg/kg Hydrogen sulphide content - mg/kg Saturated vapour pressure at recommended carriage temperature - kPa; and

.2 Environmental properties:

Distillation % recovered at 200, 340, and 370ºC.

2.2 In addition to parameters required in paragraphs 2.1.1 and 2.1.2 above, the following properties should be reported by liquid category:

.1 crude oil:

Kinematic viscosity at 20 and 50ºC - mm2/sec: Pour point temperature - ºC Cloud point temperature - ºC Reid vapour pressure - kPa Asphaltene content - % wt.

.2 residual and fuel oils, including ship's bunkers:

Parameters stipulated by table 2 of ISO 8217 Identification of differing additives and their percentage in the shipped liquid Asphaltene content - % wt

.3 unfinished distillates, hydraulic oils and lubricating oils:

Kinematic viscosity at 20 and 40ºC - mm2/sec Flash point (PMCC) - ºC Pour point temperature - ºC Cloud point temperature - ºC Reid vapour pressure - kPa Identification of differing additives and their percentage in the shipped liquid Asphaltene content - % wt

.4 gas oils, including ship's bunkers:

Parameters stipulated by table 1 of ISO 8217 Identification of differing additives and their percentage in the shipped liquid Asphaltene content - %wt

.5 kerosenes:

Total acidity - mgKOH/g Aromatic content - % volume Flash point - ºC Identification of differing additives and their percentage in the shipped liquid

.6 napthas and condensates:

Total acidity - mgKOH/g Aromatic content - % volume Flash point - ºC Reid vapour pressure - kPa

.7 gasoline blending stocks:

Aromatic content - % volume Reid vapour pressure - kPa Flash point - ºC

.8 gasolines and spirits:

Total acidity - mgKOH/g Aromatic content - % volume Reid vapour pressure - kPa Identification of differing additives and their percentage in the shipped liquid; and

.9 asphalt solutions:

Aromatic content - % volume Flash point (PMCC) - ºC Asphaltene content - % wt Identification of differing additives and their percentage in the shipped liquid Pour point - ºC.

• Informatietype: Internationaal
• Documentsoort: Resolutie
• Toegangsrechten: Intern
• Identificatie: PUC_1577_14
• Versie: 2
• Datum beschikbaarheid: 15-02-2010
• Geldigheid van: 02-06-2003
• tot en met: 30-06-2009
• Wijzigingsdatum: 19-09-2022
• Titel: 150(77) REVOKED Recommendation for material safety data sheets for MARPOL Annex I cargoes and marine fuel oils
• Organisatie: International Maritime Organization (IMO)
• Taal: Nederlands
• Onderwerp: Veiligheid / Safety
• Hoofdtaak: Koopvaardij / Merchant Shipping
• Thema: Zeevaart / Seagoing ships / Information / IMO Instruments (Informative) / Resolutions (Informative) / MSC Resolutions (Informative) / MSC/Res. 100 until 199